Investigation of the Mechanical Properties and Fracture Characteristics of Fiber-Reinforced Geopolymer Concrete Using Recycled Fibers

Document Type : Research Paper

Authors

Department of Civil Engineering, Shab.C., Islamic Azad University, Shabestar, Iran.

Abstract

Geopolymer concrete, as a sustainable alternative to Portland cement, is produced through the alkaline activation of pozzolanic materials. This type of concrete offers several environmental advantages, notably the reduction of CO₂ emissions. However, one of its main drawbacks is its relatively low flexural strength. The incorporation of fibers can enhance its ductility and reduce brittleness by bridging cracks and increasing deformation capacity.

In this study, six geopolymer concrete mix designs were prepared using 8, 10, and 12 molar sodium hydroxide solutions for pozzolan activation. To improve mechanical properties, recycled tire cord fibers were incorporated into the mixes. The specimens were cured under three different conditions: ambient temperature, 60°C, and 100°C. Compressive strength, flexural strength, fracture energy, and elastic modulus were measured for each case.

The results showed that increasing the concentration of the sodium hydroxide solution led to a 7 to 32% reduction in compressive strength, flexural strength, and modulus of elasticity, while the 8-molar solution exhibited the best performance. Using 1% recycled tire cord fibers increased the compressive strength and modulus of elasticity by 9 to 50% compared to the 2% dosage. In contrast, specimens containing 2% fibers improved the flexural strength and fracture energy by 2 to 6%, indicating enhanced toughness. Curing at temperatures of 60 and 100°C accelerated strength development, achieving 88 to 95% of the ultimate strength within 72 hours. The obtained results indicate that geopolymer concrete has the potential to replace conventional concrete, and recycled tire cord fibers improve its performance.

Keywords

Main Subjects


[1] Y. A. Al-Noaimat, S. H. Ghaffar, M. Chougan, and M. J. Al-Kheetan, “A review of 3D printing low-carbon concrete with one-part geopolymer: engineering, environmental and economic feasibility,” Case Stud. Constr. Mater., vol. 18, no. e01818, 2023, doi: https://doi.org/10.1016/j.cscm.2022.e01818.
[2] A. Goyal et al., “The physics of cement cohesion,” Sci. Adv., vol. 7, no. eabg5882, 2021.
[3] Bekun, F.V., A. A. Alola, B. A. Gyamfi, P. A. Kwakwa, and G. Uzuner, “Econometric analysis on cement production and environmental quality in European Union countries,” Int. J. Environ. Sci. Technol., vol. 20, pp. 4265–4280, 2023, doi: https://doi.org/10.1007/s13762-022-04302-9.
[4] T. K. L. Nguyen, H. H. Ngo, W. Guo, T. L. H. Nguyen, and et.al., “Environmental impacts and greenhouse gas emissions assessment for energy recovery and material recycle of the wastewater treatment plant,” Sci. Total Environ., vol. 784, no. 147135, 2021, doi: https://doi.org/10.1016/j.scitotenv.2021.147135.
[5] F. A. Shilar, S. V. Ganachari, V. B. Patil, N. Almakayeel, and T. M. Yunus Khan, “Development and optimization of an eco-friendly geopolymer brick production process for sustainable masonry construction,” Case Stud. Constr. Mater., vol. 18, no. e02133, 2023, doi: https://doi.org/10.1016/j.cscm.2023.e02133.
[6] J. Davidovits, “Geopolymer cement to minimize carbon-dioxide greenhouse-warming,” Ceram. Trans., vol. 37, pp. 165–182, 1993.
[7] D. D. B. Nergis, M. M. A. B. Abdullah, P. Vizureanu, and M. F. . Tahir, “Geopolymers and their uses: Review,” in IOP Conference Series: Materials Science and Engineering, Bristol, UK: IOP, 2018. doi: 10.1088/1757-899X/374/1/012019.
[8] A. A. Adam and X. X. X. Horianto, “The effect of temperature and duration of curing on the strength of fly ash based geopolymer mortar,” Procedia Eng., vol. 95, pp. 410–414, 2014, doi: https://doi.org/10.1016/j.proeng.2014.12.199.
[9] G. Yildirim et al., “Development of alkali-activated binders from recycled mixed masonry-originated waste,” J. Build. Eng., vol. 33, no. 101690, 2021, doi: https://doi.org/10.1016/j.jobe.2020.101690.
[10] J. Liu, X. Shi, G. Zhang, and L. Li, “Study the Mechanical Properties of Geopolymer under Different Curing Conditions,” Minerals, vol. 13, no. 5, p. 690, 2023, doi: https://doi.org/10.3390/min13050690.
[11] S. Sbahieh, G. McKay, and S. G. Al-Ghamdi, “Comprehensive Analysis of Geopolymer Materials: Properties, Environmental Impacts, and Applications,” Materials (Basel)., vol. 16, no. 23, p. 7363, 2023, doi: https://doi.org/10.3390/ma16237363.
[12] M. M. Rahman and M. A. Ahsan, “Sustainable Concrete with Fly Ash and Ground Granulated Blast Furnace Slag: A Geopolymer Approach,” Constr. Build. Mater., vol. 312, no. 125459, 2021.
[13] E. Ozcelikci et al., “A comprehensive study on the compressive strength and durability-related parameters of geopolymer mortars,” J. Clean. Prod., vol. 396, 2023, doi: https://doi.org/10.1016/j.jclepro.2023.136522.
[14] W. Song et al., “Effect of steel slag on fresh, hardened, and microstructural properties of high-calcium fly ash-based geopolymers under standard curing,” Constr. Build. Mater., vol. 229, 2019, doi: https://doi.org/10.1016/j.conbuildmat.2019.116933
[15] N. B. Singh and B. Middendorf, “Geopolymers as an alternative to Portland cement: An overview,” Constr. Build. Mater., vol. 237, no. 117455, 2020, doi: https://doi.org/10.1016/j.conbuildmat.2019.117455
[16] H. Castillo et al., “Factors Affecting the Compressive Strength of Geopolymers: A Review,” Minerals, vol. 11, no. 12, p. 1317, 2021, doi: https://doi.org/10.3390/min11121317.
[17] H. Y. Zhang, V. Kodur, B. Wu, J. Yan, and Z. S. Yuan, “Effect of temperature on bond characteristics of geopolymer concrete,” Constr. Build. Mater., vol. 163, pp. 277–285, 2018, doi: https://doi.org/10.1016/j.conbuildmat.2017.12.043.
[18] A. C. Ganesh and M. Muthukannan, “Development of High-Performance Sustainable Optimized Fiber Reinforced Geopolymer Concrete and Prediction of Compressive Strength,” J. Clean. Prod., vol. 282, no. 124543, 2021, doi: https://doi.org/10.1016/j.jclepro.2020.124543.
[19] S. Samal and I. Blanco, “An application review of fiber-reinforced geopolymer composite,” Fibers, vol. 9, no. 23, 2021, doi: https://doi.org/10.3390/fib9040023.
[20] T. Lin, D. Jia, P. He, and M. Wang, “In situ crack growth observation and fracture behavior of short carbon fiber reinforced geopolymer matrix composites,” Mater. Sci. Eng., vol. 527, pp. 2404–2407, 2010, doi: https://doi.org/10.1016/j.msea.2009.12.004.
[21] M. Ahmed and A. Abdulrahman, “Performance of Fiber-Reinforced Geopolymer Concrete: A Review,” J. Build. Eng., vol. 44, no. 103541, 2022.
[22] S. H. Ghasemzadeh Mousavinejad, and K. Faghihi. “Investigation of the fracture-based performance of heavy weight geopolymer concrete reinforced with steel fibers,” Concrete Research, 17(2), 2024, 103-113 (in persian). doi: 10.22124/jcr.2024.26649.1647.
[23] C. A. Rogers and et.al., “Recycled Tire Rubber as a Fiber Reinforcement in Concrete,” J. Mater. Civ. Eng., vol. 24, no. 10, pp. 1353–1361, 2012.
[24] M. M. Ali and Et.al., “Use of Recycled Tire Fibers in Concrete for Improved Mechanical Properties,” Constr. Build. Mater., vol. 56, pp. 113–120, 2014.
[25] ASTM C989, Standard Specification for Slag Cement for Use in Concrete and Mortars. USA: American Society for Testing and Materials, 1999.
[26] ASTM C1602, Standard Specification for Mixing Water Used in the Production of Hydraulic Cement Concrete. USA: American Society for Testing and Materials, 2004.
[27] ASTM C33, Standard Specification for Concrete Aggregates. USA: American Society for Testing and Materials, 2006.
[28] H. Yazıcı, M. Y. Yardımcı, S. Aydın, and A. S. Karabulut, “Mechanical properties of reactive powder concrete containing mineral admixtures under different curing regimes,” Constr. Build. Mater., vol. 23, pp. 1223–1231, 2009, doi: 10.1016/j.conbuildmat.2008.08.003.
[29] J. An, S. S. Kim, B. H. Nam, and S. A. Durham, “Effect of Aggregate Mineralogy and Concrete Microstructure on Thermal Expansion and Strength Properties of Concrete,” Appl. Sci., vol. 7, p. 1307, 2017, doi: 10.3390/app7121307.
[30] Y. Zhou, J. Huang, X. Yang, Y. Dong, T. Feng, and J. Liu, “Enhancing the PVA fiber-matrix interface properties in ultra high performance concrete: An experimental and molecular dynamics study,” Constr. Build. Mater., vol. 285, p. 122862, 2021, doi: https://doi.org/10.1016/j.conbuildmat.2021.122862
[31] Y. Liu, Z. Zhang, C. Shi, D. Zhu, N. Li, and Y. Deng, “Development of ultra-high performance geopolymer concrete (UHPGC): Influence of steel fiber on mechanical properties,” Cem. Concr. Compos., vol. 112, p. 103670, 2020, doi: https://doi.org/10.1016/j.cemconcomp.2020.103670.
[32] N. Li, C. Shi, Z. Zhang, H. Wang, and Y. Liu, “A review on mixture design methods for geopolymer concrete,” Compos. Part B Eng., vol. 178, no. 107490, 2019, doi: 10.1016/j.compositesb.2019.107490.
[33] G. Alaneme, K. Olonade, E. Esenogho, and M. Lawan, “Proposed simplified methodological approach for designing geopolymer concrete mixtures,” Sci. Rep., vol. 14, no. 15191, 2024, doi: 10.1038/s41598-024-15191-7.
[34] M. Rihan, R. Onchiri, N. Gathimba, and B. Sabuni, “Mix design approaches of eco-friendly geopolymer concrete: A critical review,” Hybrid Adv., vol. 7, no. 100290, 2024, doi: 10.1016/j.hyadv.2024.100290.
[35] ASTM C109, Standard Test Method for Compressive Strength of Hydraulic Cement Mortars (Using Cube Specimens). USA: American Society for Testing and Materials, 2009.
[36] ASTM C78, Standard Test Method for Flexural Strength of Concrete (Using Simple Beam with Third-Point Loading). USA: American Society for Testing and Materials, 2010.
[37] ASTM C469, Standard Test Method for Static Modulus of Elasticity and Poisson’s Ratio of Concrete in Compression. USA: American Society for Testing and Materials, 2009.
[38] ASTM C1609, Standard Test Method for Flexural Performance of Fiber-Reinforced Concrete (Using Beam With Third-Point Loading). USA: American Society for Testing and Materials, 2009.
[39] ASTM-C143, “Standard Test Method for Slump of Hydraulic-Cement Concrete,” 2003, American Society for Testing and Materials, USA.
[40] D. Hardjito, S. E. Wallah, D. M. J. Sumajouw, and B. V. Rangan, “Fly Ash-Based Geopolymer Concrete,” Aust. J. Struct. Eng., vol. 6, no. 1, pp. 77–86, 2005, doi: https://doi.org/10.1080/13287982.2005.11464946.
[41] A. C. R. da Silva et al., “Fatigue behavior of steel fiber reinforced geopolymer concrete,” Case Stud. Constr. Mater., vol. 16, p. e00829, 2022, doi: https://doi.org/10.1016/j.cscm.2021.e00829.
[42] Y. I. A. Aisheh, D. S. Atrushi, M. H. Akeed, S. Qaidi, and B. A. Tayeh, “Influence of polypropylene and steel fibers on the mechanical properties of ultra-high-performance fiber-reinforced geopolymer concrete,” Case Stud. Constr. Mater., vol. 17, p. e01234, 2022, doi: https://doi.org/10.1016/j.cscm.2022.e01234.
[43] R. F. Gomes, D. P. Dias, and F. de A. Silva, “Determination of the fracture parameters of steel fiber-reinforced geopolymer concrete,” Theor. Appl. Fract. Mech., vol. 107, p. 102568, 2020, doi: https://doi.org/10.1016/j.tafmec.2020.102568